Since the beginning of this century, the application of water-based adhesives for packaging and printing and waterborne varnish is in the ascendant stage of development. This is because water-based products not only meet the international trend of development, but also comply with China's current sustainable development policy. In 2005, the total output value of the domestic packaging and printing industry was about 300 billion yuan, while the consumption of plastic (including adhesives, varnish, and plastic film) was approximately 4.5 million tons, including the East China Market (Jiangsu, Shanghai, and Zhejiang Provinces) and the South China Market (mainly In the Pearl River Delta Region, each accounted for about two-fifths of the market share, while the rest of the country accounted for about one-fifth of the market share. The market demand for water-based adhesives and water-based varnish and water-based adhesives (including aluminized transfer adhesives) is approximately 2.5:0.5:1. That is, the market demand for water-based adhesives is about 2.8 million tons, water-based gloss oil is about 560,000 tons, and water-based adhesive glue is about 1.1 million tons.
development trend
Market demand continues to grow rapidly
The demand for most adhesives and ancillary products in China is expected to increase at a rate of more than 10%. By 2010, the total output will reach 7.3 million tons. The average annual growth rate of production is 11.5%, with a total value of 57 billion yuan. The average annual growth rate It is 11.8%.
Environmental protection and energy-saving adhesives and their accessory products accelerate development
As China has actively promoted the fundamental transformation of economic growth mode, it has taken improving the efficiency of resource utilization as the core, accelerated the adjustment of product structure and strengthened the awareness of conservation. Under the guidance of this guideline, environmental protection and energy-saving adhesive products have attracted much attention and will be developed faster. It is expected that during the “Eleventh Five-Year Plan†period, it will increase at a rate of 12% to 20% per year. Among them, the first of five series of (meth)acrylate emulsion adhesives ranked.
High-performance, high-quality and high-tech products have greater development
With the development of China's economy and the acceleration of global economic and technological integration, the demand and choice of products in the market will become more and more demanding. High-performance, multi-functional and environmentally friendly energy-saving adhesive products will be favored by the market. It is expected that these high-tech products will develop at a speed higher than 20%.
The supply of major raw materials will be greatly improved, and foreign-funded enterprises will continue to develop.
During the “Eleventh Five-Year Plan†period, the number of foreign-funded enterprises in China increased, the scale of production continued to expand, capital investment continued to increase, and high-tech products increased significantly. Many famous companies around the world have set up research centers in mainland China to strengthen the research and development of high-tech products and further improve their product quality. Companies such as Bayer, BASF, 3M, Rohm & Haas, Henkel, and Nationalstarch. It is expected that during the “Eleventh Five-Year Plan†period, foreign-funded enterprises will develop in the country with large-scale production and high-tech products. Its product sales will be increased from 40% to 45% to 50% of the total adhesive sales in mainland China.
Product production pattern accelerates to scale, intensive advantages of enterprise concentration
At present, there are many domestic adhesive manufacturers and they are small in scale. According to the statistics of 2003, there are more than 3,500 companies in the country, but there are less than 100 companies on the scale of the scale, of which 15% to 20% of companies fail each year for various reasons. Most enterprises are lagging behind in production technology, low in product quality, poor in technological innovation and scientific research and development, and aging products. They are of a single species and cannot keep up with the rapid development of the market. The reorganization of the industry and the “big reshuffling†status have become apparent, and the product production pattern has been accelerating to focus on large-scale and intensive advantaged enterprises.
Technical development trends of domestic and foreign industry products
Domestic and foreign packaging and printing adhesives, as a new type of printing accessories, have undergone new changes due to the need for environmental protection and energy conservation and consumption reduction.
Development of oily materials to waterborne materials
Such as water-based film adhesive instead of oily film adhesive, water-based varnishes instead of oily varnishes, water-based adhesives instead of solvent-based adhesives.
Single function type to multifunctional type modification
Such as: polar/polar single sticky type; paper/paper adhesive bonding to polar/non-polar bipolar adhesive modified type; paper/membrane bonding; anti-mildew, anti-cut type functional adhesive Replace ordinary glue. The use of nano-materials modified or through special synthesis techniques to make ordinary adhesive to wear, anti-adhesion, high temperature, salt fog resistance, high viscosity, flexibility and other versatility.
Manufacturing Technology Updates
Based on the design of the molecular level, a breakthrough was made in the synthesis method. In this aspect, the linear polymer structure produced by the general classical polymerization process is modified to a self-crosslinked internal crosslinking type, a diplomatic linkage type, and an internal and external multiple crosslinks by a special synthesis method; The transformation of the linear winding structure to the core-shell structure and IPN interpenetrating network structure, these technological breakthroughs are built on the level of molecular structure, and the macroscopic physical and mechanical properties of the material have been broken through the change of the microstructure.
The improvement of water-based soap polymerization to soap-free polymerization (self-emulsification) makes the water resistance, less foam, and MFT value of the product decrease, and the rheological mechanical properties of the colloid are greatly improved.
Breakthroughs in production processes and installations have shifted from labor-intensive and extensive production processes to technology-intensive and intensive production processes.
Development of internal chemical composition of products
To adapt to the needs of different substrates and different bonding methods, the main chemical composition of the main waterborne adhesive used for packaging and printing is composed of plant adhesive, animal glue, polyvinyl alcohol adhesive, polyvinyl acetate adhesive and vinegar-acrylic adhesive. , EVA glue to polyacrylate glue to polyurethane glue, polyurethane modified acrylic glue direction. Among them, depending on the purpose of use, in combination with the need of economic cost, there is a cold blending modification in which the glue is blended with another glue or a plurality of glues. A more advanced approach is to blend a variety of major chemical components that are needed in the former and to manufacture them by copolymerization, such as polyurethane-modified polyacrylate adhesives. This can be expected to obtain better integrated application performance.
Development of Bonding Theory in Application
Bonding theory includes physical adsorption bonding theory, chemical bond bonding theory, weak boundary layer bonding theory, diffusion bonding theory, electrostatic gravitation bonding theory, and mechanical force bonding theory, etc. In addition to the mechanical force bonding theory, there will be some technological breakthroughs in the two aspects of the synthetic production and application of adhesives. For example, some functional monomers and functional auxiliaries will be introduced to improve the bonding behavior between the same interface and different interfaces; some new methods will be used in the design of synthetic molecular structures, such as the synthesis of IPN structures and self-crosslinking structures. , Core-shell structure or soap-free emulsion polymerization method; in the change of the rheological mechanical properties of the colloid, improve the colloid on the substrate wetting and leveling performance, the role of functional additives is very important. The basic starting point for technological improvements or technological breakthroughs that occur is closely related to the application of adhesive bonding theory. At the adhesive application level, the chemical properties of the substrate must first be considered, and then adhesives of different properties should be selected under the guidance of bonding theory to suit the chemical properties of different substrates. In recent years, the bonding theory has a very important significance to guide the synthesis of adhesives, to explain the adhesive wetting, rheology, infiltration, superposition behavior research and to understand the nature of the interface bonding.
Outdoor bench refers to the seating facilities used in outdoor places, often commonly found in parks, squares, leisure areas, scenic spots and other outdoor environments. The classification of outdoor benches can be introduced according to many aspects such as material, shape and function.
First, classification by material
1. Wooden bench: Wooden bench is one of the most common outdoor benches, usually made of natural wood, with natural and environmentally friendly characteristics. Wooden benches are usually made of solid wood or artificial wood, and the surface is treated with waterproof and anti-corrosion, which can adapt to various climatic conditions in the outdoor environment.
2. Metal bench: Metal bench is made of metal materials, such as cast iron, steel, etc. The metal bench is durable, corrosion resistant, easy to clean and is suitable for all kinds of outdoor environments.
3. Stone bench: Stone bench is made of marble, granite and other stone, which has the characteristics of good texture and beautiful appearance. Stone benches are generally suitable for high-end places such as garden scenic spots and can be integrated with the surrounding environment.
5. Combined material bench: Combined material bench refers to the bench made of different materials, such as the combination of wood and metal, stone and plastic combination. Combined material bench can usually combine the advantages of different materials, more in line with the needs of different outdoor environments.
2. Classification by shape
1. Linear bench: Linear bench is the most common shape of bench, generally composed of a row of seats, forming a straight line arrangement. The linear bench is suitable for outdoor places with large pedestrian flow and can provide more seats.
2. Arc bench: Arc bench is an arc bench composed of multiple seats, usually used in a ring seat area or landscape area. The curved bench can not only provide comfortable seating, but also increase the aesthetics of the place.
3. Wavy bench: The wavy bench is a bench composed of multiple seats in the shape of undulating waves, giving people a sense of movement and flow. The wavy bench is suitable for parks, squares and other places that need to increase vitality and fun.
4. Round bench: A round bench is a round bench composed of a number of seats, which is usually used in outdoor recreation areas and can provide a place for groups to gather.
3. Classification by function
1. Leisure bench: Leisure bench is a common form of outdoor bench, it can provide comfortable seats, so that people can relax in the outdoor environment.
2. Viewing bench: Viewing bench is usually set in a scenic outdoor environment, providing comfortable seats for people to enjoy the scenery.
3. Sitting bench: Sitting bench is usually set in parks, squares and other places with large traffic, to provide people with a short rest and relaxation.
4. Cool pavilion bench: Pavilion bench refers to a form of combination of bench and pavilion, which can provide sunshade, rain prevention and other functions, suitable for outdoor leisure areas.
In short, the classification of outdoor benches can be divided from many aspects such as material, shape and function. Different outdoor environments and needs need to choose a suitable bench type to provide comfortable and beautiful seating facilities
Beach Bench,Deck Chair,Deck Bench,Waterproof Bench
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